A bow is made of horse hairs that are connected on each end to a stick that is typically made of wood or a synthetic material. On their own, the hairs on a bow are very smooth; so if you were to rub them across the strings of a violin without putting on rosin, the bow would simply slide across the string without causing the strings to vibrate, which means no sound.
When rosin is applied, it gives the bow some stickiness. This will increase the friction between the hairs on the bow and the string. Because of this friction, the bow will try to stick a little to the strings. It will grab the strings, causing them to vibrate as you drag your bow across. This is part of what makes a violin have such a clear sound. You have to reapply rosin every now and then. You start to notice that your violin isn't making much sound, especially when playing higher notes, when it is in need of more rosin.
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